1971

The Brit actor fell head over heels for Shakira after spotting her in a Maxwell House advert, then a colleague of his arranged for him to meet her. As the fairytale would go, the two fell in love and married in 1974. And despite Caine working with some of Hollywood's hottest women, he said of his wife: "I married a woman who in actual fact is more beautiful than most women I have worked with."